Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ2 N 1,N 5)nickel(II) methanol monosolvate
نویسندگان
چکیده
The title compound, [Ni(C4H8N3)2]·CH3OH, contains two independent Ni(II) atoms, each located on an inversion center and coordinated by four N atoms from two 1-[(1-imino-eth-yl)imino]-eth-yl}aza-nide ligands in a square-planar geometry. N-H⋯N, N-H⋯O and O-H⋯N hydrogen bonds link the complex mol-ecules and methanol solvent mol-ecules into a corrugated layer parallel to (001).
منابع مشابه
Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2 O,N 4]copper(II)
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متن کاملBis[2-(1-iminoethyl)phenolato-κ2 N,O]nickel(II)
There are one and a half independent mol-ecules in the asymmetric unit of the title compound, [Ni(C(8)H(8)NO)(2)], one of which is situated on an inversion center. In both mol-ecules, the Ni(II) ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar geometry. Inter-molecular N-H⋯O hydrogen bonds link three mol-ecules into centrosymmetric trimer....
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013